Will there be wars over elements like there have been over petroleum and water? What element have we been using in color televisions? What substance is used to make energy saving, environmental light bulbs?

Each of the elements found in the periodic table have their own characteristics. After they have been cooked in the pot of the universe, these substances that are offered to our service can be radioactive (like uranium), metallic (like magnesium) and even gaseous (like helium). Seventeen of the elements not easily found among the layers underground have unique properties. These elements are called rare-earth elements, because it is hard to discover and mine them.

Rare-earth elements are in many of our everyday devices. The data projected on a computer screen is transmitted via optic cables containing erbium. The light of a tablet device is generated by the phosphorescent element europium. We actually touch indium covered surfaces when we scroll our fingers on touch screen monitors. When listening through headphones, we are using neodymium magnets that are ten times stronger than iron magnets.

From space technologies to defense industries, from cell phones to LED lighting, many such rare-earth elements are used in every stage of our lives. These elements – many of which we cannot live without, even though we’ve never heard of them – were recorded into the Critical Materials Strategy Document published by the U.S. Department of Energy in 2010. In a public announcement, the department declared fourteen of the elements as specially significant regarding clean energy, listed six of them as critical, and the other four as near critical. Fifteen elements, beginning with lanthanum and ending with lutetium, numbered between 57 and 71, comprise lanthanides. Combined with scandium and yttrium, these make up the seventeen rare-earth elements.

The elements that we touch on screens

Indium (atomic number 49) gains the properties of electrical conductivity and optic transparency when combined with tin, which, at number 50, is indiums’s neighbor on the periodic table. Optical transparency is a desired property for plasma screen and television technologies. Indium is also an important material for mobile phone touchscreens. Interestingly, when indium combines with cadmium, also as a neighbor at number 48, it loses the optical transparency. Instead, it is able to absorb light. Light harvesting is a very critical feature in the production of solar cells.

The relationship of indium with its two neighbors opens new horizons for scientists. In the near future, it is hoped that many unknown and interesting features will be unearthed by investigating the known elements of the periodic table. It is amazing that these elements have been around for thousands of years in the universe only to be discovered by technological advancements.

The need for rare-elements in the world is around fifty thousand tons. The current recorded reserve for rare-earth elements is 110 Million tons. Currently, 95% of the demand for rare-earth elements is supplied by China, yet the country only has 35% of the world’s reserves. Therefore scientists are constantly searching for rare-earth element mines to eliminate the Chinese monopoly and to boost the production of these rare materials. In recent years, China has gotten into political debates with Japan and the United States by curbing rare-earth element exports. Economic journals covering these debates wondered if “element wars” were near. In 2010, a massive reserve of elements, enough to sustain worldwide demand, was discovered in the Pacific Ocean. Developed countries are now planning to recycle rare-earth elements from used devices due to low reserves.

Yttrium, europium, and terbium (atomic numbers 39, 63 and 65) have been known for a long time. Terbium and yttrium are named after the Swedish town of Ytterby. Yttrium is the first rare-earth element discovered, at the end of 18th century. Plastics containing europium are used to make laser products; it’s also used as an element to provide the red color on television screens. Yttrium has a supplementary role that enhances europium’s red color production. And terbium oxide activates the green phosphorescence of television tubes with its yellow-green phosphorescent property.

Terbium also enables an 80% reduction of energy consumption in light bulbs. This makes it one of the most wanted elements in the $2 billion rare-earth element market. Today, when we purchase class A type light bulbs, we are actually buying rare elements like terbium.

Neodymium (number 60), which emits a green light via laser pointers, is also used in the magnets of electric motors. When neodymium combines with boron and iron, it makes a magnet twelve times stronger than simple iron magnets. Because it is significantly less dense than iron, it makes electric motors and laptop computers much lighter. Another interesting feature of neodymium is that it enhances the data storage capacity of hard drives. Furthermore, neodymium is wanted for electrical devices and wind turbines.

The union of elements

Dysprosium was discovered in 1886 and can never be found in a free form in nature. This is because it exists in a compound form with other minerals, like gadolinite. Dysprosium is also known for its magnetic property, and when mixed with terbium and iron, it forms a substance called Terfenol-D. In a magnetic field, Terfenol-D has unique transformational abilities. Dysprosium is utilized in laser production together with vanadium, and it emits infrared radiation when used with cadmium.

The magnetic alloys of iron, boron, and neodymium lose their magnetic features beyond 300 degrees Celsius. However when this alloy is combined with dysprosium at a 5% ratio, that problem disappears. Therefore, these magnets are used for electric turbines and hard disc motors. Dysprosium also makes magnets in electric motors 95% lighter. And dysprosium and nickel mixed fillings are used as cooling rods in nuclear reactors.

The human mind becomes fascinated after seeing all the wisdom and properties involved in these lifeless elements. Either we conclude that these elements have doctorate degrees in physics and chemistry from Harvard University, or we may express our weakness and fascination in front of The Grand Creator who created and presented these elements for our benefit.

Is the yellow color in glasses from the planet Ceres?

Since Dell recalled four million laptop computers in 2006, because of a possible explosion caused by overheating battery, scientists’ eyes have been focused on lanthanum and cerium. These two elements are considered to be safer than other alternatives. Lanthanum and cerium are used in electrical equipment and energy saving light bulbs, and are classified as critical elements in these processes, along with tellurium. Cerium, named after the planet Ceres, is responsible for the yellow coloration in glasses. Cerium is also used in polishes, ceramics, and petrol refineries. Tellurium is produced indirectly, unlike most other elements. The production of cadmium takes place during zinc production, and tellurium during copper refining. Tellurium is a cheaper element that has been used in combination with cadmium on solar cells since 2009; before then, most solar cells used expensive silicon panels.

Elements in our lives, from space rockets to ultrasound imaging

Hafnium, tantalum, erbium, and technetium are important elements, even though they are not listed critical. Even though hafnium and technetium are not rare-earth elements, they were still added to the critical material strategy document produced by the US Department of Energy. Hafnium is employed in space rockets for its resistance against extreme temperatures and wearing. Hafnium oxide is a valuable material for electronic transistors since it is a very effective electric insulator. It is 20% faster than the silicon oxide that is commonly used in transistors. A transistors length is around 65 nanometers when silicon oxide is used, but it is only 32 nanometers with transistors made of hafnium oxide. This 50% decrease enables smaller devices.

Touchscreens containing indium, laptop computers powered by lithium ion batteries, and cell phones with hafnium transistors are some of today’s technological wonders. Would these inventions still be possible without these elements? Could we reach the high capacities in hard discs without the tantalum? Would we be able to protect ourselves from electric leakage in computers without high quality electric insulators such as tantalum oxide?

Radioactive technetium, which was discovered in 1937, is the first artificially produced element. The technetium 99 isotope is used in nuclear medicine. Technetium produced from uranium has a half life of 211,000 years, as opposed to the 6 hour half life of the technetium 99 isotope. The number of technetium based nuclear medicinal tests, like ultrasounds and x-ray imaging, is estimated to be above thirty million annually.

We take advantage of these elements in every stage of our lives, from medicine to technology. Could we become dependent upon elements the way we are upon petroleum? Only time will tell. Either these elements will be replaced by other materials, or other technologies will outdate the current technologies. It is also possible new elements will be discovered.

A majority of our modern technologies would not exist without these elements that were dispersed among the earth billions of years ago. These elements were placed here for our benefit, and so we could utilize them, and produce institutes of scientific research and education to study them.

Kadir Can and Mehmet Ramazanoglu are science teachers in Ankara, Turkey.

Nanoscience and nanotechnology started off in the early 1980s when scientists were able to detect materials on the nano-level through microscopic systems. This development enabled the synthesis of nano-level materials such as carbon nanotubes, nano crystals, and metal oxide nanoparticles. Nanotechnology is a type of technology, resulting from the research conducted on the atomic, molecular and macromolecular levels. A nanometer is one-billionth of a meter. Nano-level studies are conducted with materials whose sizes range between one to a hundred nanometers. Studies on the nano-level are conducted in the contemporary science fields such as chemistry, materials science, physics, biology, etc. One of the most compelling reasons that renders the research with nano-level materials so significant is that nanoparticles reflect a lot more different characteristics than when they do at the macro-level. Due to their small sizes, nanoparticles, especially those under 20 nm, have magnificent optical, magnetic, and chemical properties.[1] Nanoparticles include much more energy than the macro-level materials; this is because the ratio of the surface area of nanoparticles to their volume is much more bigger than the ratio in macro-level materials. A significant amount of energy is stored in nanoparticles as free surface energy. This energy revealed on the nano-level not only increases the reactivity of iron nanoparticles (the propensity to chemical reactivity), but also renders the magnetic qualities of materials quite differently than they would be at the macro-level.

Many types of nanoparticles are widely used in our daily lives. Iron, gold, silver and cadmium sulphide nanoparticles are some of the most commonly investigated nanoparticles. Yet iron nanoparticles receive special attention from scientists essentially in the field of biotechnology. Iron nanoparticles demonstrating different magnetic features have a wide range of use in fields, including but not limited to health care and electric/electronic industry. Owing to its magnetic feature, iron is also used in magnetic recording. The production of needle-shaped iron nanoparticles with high magnetic features has facilitated the manufacturing of mobile electronic devices with a high recording capacity. In this paper, we will focus on the use of iron nanoparticles’ contribution to the advances in the field of biotechnology, among numerous other contributions of iron nanoparticles in other fields.

Nanobiotechnology

Nanobiotechnology, among other fields of nanotechnology, is the field that focuses on biological systems. Nano-level devices designed to work with biosystems, nano-level cell biology, cell and nanoparticle interactions are some of the applications used in nanobiotechnology. Through those applications, biochemical processes and reactions in living beings can be scrutinized in great detail, which, in turn, enables scholars to come up with innovations in both diagnosis and treatment of various illnesses.

The following are the primary application areas of magnetic nanoparticles in the field of bionanotechnology: development of magnetic resonance imaging systems, and cancer research. Especially, iron oxides (magnetite, Fe3O4, maghemite, Fe2O3), owing to their cohesion with the chemical structure of biological systems, are prevalently used in biotechnology.

Magnetic Resonance Imaging (MRI)

MRI, mostly used in the medical field, is the method to monitor the internal structure of living mechanisms. Through the magnetic area and radio frequency waves, the image of a living tissue is formed. MRI is a complex system that produces images based on the intensity and movements of hydrogen atoms in the tissue. The MRI technique is used to diagnose almost all sorts of illnesses today. Yet it is most frequently used with illnesses pertaining to the central nervous system, brain and spinal cord. It has also been used to diagnose muscle-related and skeleton-related medical conditions, such as meniscus and herniated disc symptoms, as well as all types of neurological illnesses. MRI has not been found detrimental to any living organism thus far.

It is the paramagnetic ions such as gadolinium that are most frequently used as contrast enhancement agents in MRI applications. Although gadolinium has a high moment, this moment is too low compared to superparamagnetic materials. For this reason, superparamagnetic iron oxide nanoparticles are known to be more efficient MRI contrast enhancement agents. Known as such, those iron oxide nanoparticles are quite advantageous over gadolinium. Those nanoparticles can easily be functionalized to interact with biological samples. For example, superparamagnetic nanoparticles, which are not normally taken up by cells efficiently, can do so after being covered with another material (e.g. Dextran) that can ordinarily go into a cell. Thus, MR images of particular tissues could be obtained clearly, which enables us to make more accurate diagnoses and treatments.

Iron oxide nanoparticles are also deemed to be an efficient potential future method in cancer treatment. The results of several studies conducted to fulfill this goal are encouraging.

Iron oxide superparamagnetic nanoparticles are being tested as a method in hyperthermia treatment. Hyperthermia is defined as an abnormally high body temperature, and its treatment is carried out through the removal of certain tissues by increasing its temperature up to (42–46) 0C for 30 minutes. For instance, cancer infected liver tissues are exterminated through the hyperthermia method, which sends biologically activated iron oxide nanoparticles to those infected tissues. Moreover, none of the healthy tissues are damaged during this process. You may find more detailed information in references [1, 2, 4, 6] on how nanoparticles are aptly sent to the cancer infected tissues only while the surrounding healthy tissues remain unaffected by them. Hundreds of researchers carry out experiments and publish their findings on this topic everyday. Yet, further research needs to be done in order to reach solid conclusions.

Iron, which seems to carry greater potential significance than we previously thought, should receive much attention from scholars due to the fact that a chapter (surah) in the Holy Qur’an is entitled “Iron” (Hadeed). The question is, why was a 29-line chapter in the Qur’an is called (Iron) when the word “iron” was only mentioned once throughout the entire chapter.

The chapter “Iron” first begins by drawing the reader’s attention to the attributes and praised names of God. It invites people to believe in God and his messenger Muhammad (peace be upon him) by exalting God as the Almighty, Sovereign, Ruler, One whose existence is without a beginning and an end, Manifest and Hidden. Then, the chapter goes on to encourage believers to donate their wealth for the sake of God, for those who follow the word of God are rewarded with a place in Heaven. It also advises believers never to lose their ardor, while reminding them that even the earth will be resurrected after all has perished. And the wisdom behind the creation of iron is explained as such:

Assuredly We have sent Our Messengers with manifest truths (and clear proofs of their being Messengers), and We have sent down with them the Book and the Balance so that (relations among) humankind may live by equity. And We have sent down iron in [the essence] which is stern might and benefits for humankind, so that God may mark out those who help (the cause of) God and His Messengers, though they do not see Him. Surely God is All-Strong, All-Glorious with irresistible might. (57:25)

This particular verse includes several remarkable points. First, the very use of the phrase “sending down” for iron is so striking that it was also mentioned in [3, 5]. Another perplexing statement is, We sent down iron in [the essence] which is stern might and benefits for humankind, which might pave the way for thought-provoking venues regarding nanotechnology. The verse also indicates that which makes iron so special, its indiscernible or hidden qualities, rather than the outer surface of it. The specific reference to the “essence” of iron hints at this point. If the message of the verse had been related to the external qualities of iron, then the choice of the words would differ accordingly. Since the Qur’an is the word of God, there is wisdom behind the selection and sequencing of each word and letter. From this point of view, we can interpret that this verse informs us about the significance of the essence of iron on the nano level.

The significance of iron as stated in a single verse of the Qur’an has been briefly discussed. Numerous studies on the use of iron in nanotechnology seem to be on the horizon, which will only contribute to our admiration for the miracle of the Qur’an.

Kamil Ezgin is pursuing a PhD degree in chemistry in USA. For correspondence with the author kamilezgin@gmail.com.

References

1. Dale L. Huber. Synthesis, Properties, and Applications of Iron Nanoparticles, small, 2005, 1, No. 5, 482-501.
2. An-Hui Lu, E.L. Salabas, and Ferdi Schuth, Magnetic Nanoparticles: Synthesis, Protection, Functionalization, and Application, Angew. Chem. Int. Ed. 2007, 46, 1222-1244.
3. Edib Masûkî. “Enteresan Bir Tespit: Demirin Sakladiði Sir,” Sizinti, 1985, No. 73.
4. Peter Majewski and Benjamin Thierry. “Functionalized Magnetic Nanoparticles- Synthesis, Properties, and Bio-Applications,” Critical Reviews in Solid State and Materials Sciences, 2007, 32, 203-215.
5. http://www.mergeous.com/bullet.asp?tag=72
6. Volker Mailander and Katharina Landfester, “Interaction of Nanoparticles with Cells,” Biomacromolecules 2009, 10, 2379–2400.